DC will not replicate in sites/services

I have a new 2008 r2 DC that is also holding user profiles that will not replicate in sites and services..

I am getting 1865/1311/1566 AD KCC errors.

trying to replicate manually in sites and services gives me THe Remote Procedure call failed and did not execute

It runs / resolves users get their profiles etc. however

I have actually tried to dcpromo to remove it from the domain but I get an error on reaching the main DC.

I checked dns, flushed/registered the cache.

trying to repadmin /bind to another server gives me an ldap 81 error

ANyone been thru this mess?

Help! Thanks :-D